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2 edition of Crystallization and crazing in polycarbonates found in the catalog.

Crystallization and crazing in polycarbonates

B. C. Cope

Crystallization and crazing in polycarbonates

  • 370 Want to read
  • 11 Currently reading

Published by Leicester Polytechnic School of Chemistry in Leicester .
Written in English


Edition Notes

Thesis (Ph.D.) - Leicester Polytechnic, Leicester 1977.

StatementB. C. Cope.
ContributionsLeicester Polytechnic. School of Chemistry.
ID Numbers
Open LibraryOL17894446M

5Salt Crystallization This chapter treats the damage of structural concrete by salt crystallization. This phenomenon is also termed “salt weathering” for other porous building materials, such as stones and - Selection from Durability Design of Concrete Structures [Book]. Crystallization can be a powerful separation tool in a broad range of industries. But to optimize it, you must clearly understand the process. Join crystallization expert Wayne Genck for a practical overview of the basics of crystallization and precipitation and how to apply the fundamentals of crystal growth and nucleation to industrial processes. This exquisite design is made from tough polycarbonate plastic, these beautiful champagne flutes are unbreakable and dishwasher safe. Unlike regular acrylic, polycarbonate resists cracking, clouding and crazing. They offer glass like beauty and lasting worry-free strength. Perfect for indoor and outdoor entertaining. UnbreakableBrand: Prodyne.   Crystal vs Glass When it Comes to Wine Glasses. Crystal glass doesn’t actually have a crystalline structure (e.g. a quartz rock), but the name stuck because it sounds a lot less menacing than lead glass (which is what crystal glass actually is). So for the sake of convenience, we’re going to keep calling it that you can too.


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Crystallization and crazing in polycarbonates by B. C. Cope Download PDF EPUB FB2

The purpose of this study was to characterize the craze growth behavior of Crystallization and crazing in polycarbonates book (PC) as a function of stress level, model the residual mechanical properties of PC at various craze levels and strain rates, and determine if the total surface area of crazing is the sole factor in residual properties or if the crazing stress plays a by: 2.

Search within book. Front Matter Edward J. Kramer. Pages Intrinsic crazes in polycarbonate: Phenomenology and molecular interpretation of a new phenomenon.

Manfred Dettenmaier. Pages Optical interference measurements and fracture mechanics analysis of crack tip craze Crystallization and crazing in polycarbonates book. Döll. Pages Crazing and fatigue behavior.

Abstr acid aliphatic amorphous annealing Appl applications aromatic polycarbonates Bayer AG behavior Bendler birefringence bisphenol bisphenol-A blends block copolymers bonate Crystallization and crazing in polycarbonates book branched polycarbonate chain Chem chemical correlation crazing crystalline crystallization D.

LeGrand diphenyl carbonate ductility effects equation Figure film 5/5(1). In Crystallization of Polymers, second edition, Leo Mandelkern provides a self-contained, comprehensive, and up-to-date treatment ofpolymer crystallization.

All classes ofmacro-molecules are included and the approach is through the basic disciplines ofchemistry and physics. The book discusses the thermodynamics and physical properties that.

Purchase Crystallization - 1st Edition. Print Book & E-Book. ISBNBook Edition: 1. The book covers current knowledge on all aspects of polyester synthesis, structure, properties (chemical, physical and application relevant) and recycling.

The most important technical polyesters are presented in detailed chapters, homogeneous polymers as well as copolymers, blends and high-performance reinforced polyester materials are discussed.

Crazing Crazing is also called hairline craze. They can be fine, thin, tiny type cracks that may extend in an unreinforced or reinforced plastic network on or under the surface or through a layer of a plastic material.

Different conditions and effects occur depending on the type plastic, load conditions, and environment. crystal growth condition) to avoid damaging the crystal while achieving a reproducible (isomorphous) end point.

Radiation-induced Damage X-ray exposure damages proteins, resulting is a Crystallization and crazing in polycarbonates book decline in diffraction quality (decreased diffraction intensity, increased mosaicity, streaking, etc.).File Size: KB.

Process Engineering Laboratory II Crystallization Introduction Crystallization is a separation process, widely applied in the chemical and pharmaceutical indus-try.

The principle of crystallization is based on the limited solubility of a compound in a solvent at a certain temperature, pressure, etc. A change of these conditions to a state where. Crazing translates to fine cracks in the glaze or surface layer of porcelain wares.

It can also occur in pottery, some plastics, and composition materials (such as the face of a composition doll that has not been properly stored). This type of damage is caused by the difference in the contraction rate in the body material of an object compared.

Crazing is a "micro-scopically localized" phenomenon that involves a highly concentrated state of localized stresses and is driven by the formation of drawn fibrils of the polymer that span the. Introduction General Introduction. The reaction of polyhydroxy compounds with some carbonic acid derivatives results in a series Crystallization and crazing in polycarbonates book related polymers with carbonate (OCOO) linkages, and these polymers are referred to as polycarbonates (PCs).PCs were first prepared by Einhorn () by reacting hydroquinone (1, 4-dihydroxybenzene) and resorcinol (1, 3.

Temperature-modulated DSC (TMDSC) measurements at reasonably high frequencies allow for the determination of base-line heat capacity. In this particular case vitrification and devitrification of the Crystallization and crazing in polycarbonates book amorphous fraction (RAF) can be directly observed.

Hz seems to be a reasonably high frequency for bisphenol-A polycarbonate (PC). The RAF Cited by: Crystallization is a Crystallization and crazing in polycarbonates book and purification technique employed to produce a wide variety of materials.

Crystallization may be defined as a phase change in which a crystalline product is obtained from a solution. A solution is a mixture of two or more species that form a homogenous single phase. Solutions are normally thought of in termsFile Size: KB.

This crystallization theory is widely accepted to describe the physical behavior of a variety of crystallization process, for instance, semi-crystallization in polymer, polymer blends, and.

Crystallization is practiced on all scales: from the isolation of the first milligrams of a newly synthesized substance in the research laboratory to isolating products on the mulit-million tonne scale in industry. The book describes the breadth of crystallization operations, from isolation from a reaction broth Format: Hardcover.

Controlling molecular mobility and ductile-brittle transitions of polycarbonate copolymers. Journal of Polymer Science Part B: Polymer Physics39 (15), DOI: /polb Stephen B. Clay, Ronald G.

Kander. A new method to quantify crazing in various by: POLYCARBONATE (PC) Physical and mechanical properties: Polycarbonate is a polymer which, when uncrystallized, has excellent transparency.

When thick, it has a slight yellowish tint. The index of refraction of transparent and colorless PC is very high, The industrial grades of PC have molecular weights on the order of 20, to 50,e Size: KB. Crazing is the phenomenon that produces a network of fine cracks on the surface of a material, for example in a glaze layer.

Crazing frequently precedes fracture in some glassy thermoplastic polymers. As it only takes place under tensile stress, the plane of the crazing corresponds to the stress direction.

Crystallization is used at some stage in nearly all process industries as a method of production, purification or recovery of solid materials. Incorporating all the recent developments and applications of crystallization technology, Crystallization gives clear accounts of the underlying principles, a review of the past and current research themes and guidelines for equipment Reviews: 1.

The stress‐cracking of polycarbonate by a gaseous or liquid agent results from the diffusion of this agent into the polymer. The low molecular weight polymer fractions and the chain ends within the bulk of the polymer become more ordered during the diffusion and swelling process by their partial solubility in the crazing agent, causing by:   The effect of lattice defects on the physical properties of metals is also considered.

Comprised of nine chapters, this book begins by providing a short and, where possible, precise explanation of dislocation theory. The first six chapters discuss the properties of dislocations and point defects both in crystals and in an elastic Edition: 1.

Wash Lexan Sheet with a mild soap or detergent (e.g., Joy** dishwashing liquid) and lukewarm water using a clean sponge or a soft cloth.

Rinse well with clean water. Dry thoroughly with a chamois or moist cellulose sponge to prevent water spots. Do not scrub or use brushes on these products: their coating is UV-resistant, not mar-resistant. Polycarbonate resists cracking, clouding and crazing. These pieces offer glass-like beauty and lasting worry-free strength.

Items shipped bulk pack with clear "static" label that points out the unbreakable, dishwasher safe features of polycarbonate Made from tough polycarbonate plastic, this classically styled collection is unbreakable and Brand: Prodyne.

In this study, we report a systematical investigation regarding the ring size effects of meso-epoxides on reactivity and enantioselectivity as well as crystallization and degradation of the polycarbonates resulting from the asymmetric alternating copolymerization of various alicyclic epoxides (cyclopentene oxide, cyclohexene oxide, cycloheptene oxide, and cyclooctene oxide).

Shear Banding vs. Crazing • Shear banding occurs if the number of entanglements per chain is large so that the crazing stress is higher than the yield stress. • Crazing occurs if the yield stress is lower, for example if the molecular weight is low (few entanglements) or the temperature is high (constraint release).

Addeddate Identifier Crystallization4thEdition Identifier-ark ark://t9t15vw4w Ocr ABBYY FineReader Ppi Solvent-induced crystallization of a polycarbonate surface and texture copying by polydimethylsiloxane for improved surface hydrophobicity B.

Yilbas,1 H. Ali,2 N. Al-Aqeeli,2 M. Khaled,3 N. Abu-Dheir,2 K. Varanasi4 1Mechanical Engineering Department and Excellence in Renewable Energy, King Fahd University of Petroleum and Minerals, DhahranSaudi File Size: 1MB.

Crystalline glazes. A type of ceramic glaze made by potters. Giant multicolored crystals grown on a super gloss low alumina glaze by controlling multiple holds and soaks during cooling Details. Crystals can form during cooling and solidification in many kinds of glazes and they can be microscopic or very large, widely scattered or completely.

Stress Crazing On Acrylic Surfaces And Its Causes Stress crazing, which appears as an area of tiny micro-cracks, occasionally shows up in areas on the surface of most thermoplastic sheets. This phenomena, although rare and preventable, is known to occur in many types ofFile Size: 88KB.

Crystallization of polymers is a process associated with partial alignment of their molecular chains. These chains fold together and form ordered regions called lamellae, which compose larger spheroidal structures named spherulites. Polymers can crystallize upon cooling from melting, mechanical stretching or solvent evaporation.

Crystallization affects optical. The books, frozen in a myriad of positions by the crystal growth, have become artifacts or geologic specimens imbued with the history of time, use, and nostalgia.”. The latter phenomenon is often called solvent-induced crystallization, and was observed during the absorption studies discussed above.

The nominally amorphous PET, PCTG, and polycarbonate films turned opaque upon exposure to certain solvents (see italicized data in Table III), indicating that crystallization had occurred. tions - a glass transition about 80°C, a cold crystallization peak at °C and a melting peak at °C.

In addition, although there is no clear indication of a transition between the cold crystallization and the melt, the fibaselinefl has an apparent exothermic bump prior to the onset of Size: KB.

A new method to evaluate solvent stress cracking. Link/Page Citation be used later to study the effect of crazing on the crystal morphology by etching the crazed samples and comparing the resultant structure with Fig.

Stress cracking and photodegradation behavior of polycarbonate. The combination of two major causes of polymer failure. catalog books, media & more in the cystallinity-- commerical applications of polycarbonate-- part assembly-- secondary finishing-- current applications of polycarbonates.

(source: Nielsen Book Data) -- viscoelasticity of glassy and semicrystalline polymers-- flow behaviour of polymer melts and solutions-- yield crazing and fracture. The results quantitatively displayed the effect of stress and temperature on the crazing rate of polycarbonate.

As expected, the crazing rate increased with increasing stress and temperature. In the stress and temperature ranges tested, the time to initiate crazing is difficult to define due to the time resolution of the test setup.

Shop at the Amazon Dining & Entertaining store. Free Shipping on eligible items. Everyday low prices, save up to 50%/5(2). 1 Material Properties of Plastics Formation and Structure The basic structure of plastics (or polymers) is given by macromolecule chains, formulated from monomer units by chemical reactions.

Typical reactions for chain assembling are polyaddition (continuous or step wise) and condensation polymer-ization (polycondensation) [1] (Figure ). Stress-Strain Behavior of Polymers One of the most important characteristics of polymers is their inherent toughness and resistance to fracture (crack propagation).

It is not coincidence that the name plastic, which describes any kind of polymeric material, is similar to the word plasticity which is the propensity of a solid to undergo. title = "Properties of blends of polycarbonate and pdf (I): Crystallization behavior", abstract = "Blends of polycarbonate (PC) and polypropylene (PP) have been investigated by differential scanning calorimetry and polarized-light : Y.

S. Chun, H. S. Lee, T. S. Oh, Woo Nyon Kim.Nanostructured polyamide 12(PA12)/polyketone (PK) blends were fabricated by melt compounding.

The nanoscale droplet and domain-in-domain download pdf depending on PK content were observed. When the content of PK was 10 vol %, the impact strength of the blend jumped from to kJ/m2 and further improved with an increasing content of PK. The Cited by: 2.L-3 Crystallization “Crystal growth is achieved by ebook slow dehydration of the water of solvation from the sample in a controlled manner that prevents precipitation and takes the sample out of solution and into a crystalline state.”File Size: KB.